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Relationship of Impact Strength, Tensile Strength and the Fiber-Matrix Interface in varieties of Polypropylene Long-Glass Fiber Injection Moldings

Paper (6-2-8) to the 10th International Annual Meeting of the Polymer Processing Society, Akron, USA, 5th-8th April 1994.

S F Bush with D R Blackburn, O K Ademosu, F B Yilmaz and P F Zhang

Introduction

Earlier papers(1, 2, 3, 4) have described the factors affecting fiber-matrix cntacting, the organization of long fibers into coherent lace-like or mat-like structures, and the dependence of tensile strength on these two classes of variable. Equations for the mean number of touches1 in the fiber structure and tensile strength2 have been proposed which allow for the main variables present in moldings and extrusions, including differing matrix properties. Fiber management technology developed under the generic acronym SAFIRE4 (Self Assembling Fiber Reinforcement) has recently been applied commercially to practical moldings such as hard hats and pallets, in both of which examples impact strength is a key property.

Accordingly, a wide series of experiments has been carried out using the Izod method to determine the variation of impact strength as a function of the fiber length, fiber concentration, the fiber-matrix interface, fiber reinforcement structure and matrix properties. Both commercially available long-fiber granules and laboratory-compounded types have been used with different mold configurations and molding conditions for a variety of polypropylene and polyethylene matrices.

References

[1] S F Bush, Control of Fiber Structures in Melt Extrusion, 36 Ann Mtg Can Soc Chem Eng, Sarnia, Canada (1986) paper 32d.

[2] S F Bush, O K Ademosu, D R Blackburn, F B Yilmaz, Factors Affecting the Strength of Long-Fibre Reinforced Injection Moldings, Poly Proc Soc Eur Mtg, Prague (1992) paper 6-06.

[3] D R Blackburn and O K Ademosu, Factors Affecting Fiber-Matrix Contacting in Fiber-filled Granules, Poly Proc Soc, 9th Ann Mtg, Manchester 1993, Paper 6-14.

[4] S F Bush, Self Assembling Fibre Reinforcement (SAFIRE) processes, “Textile-reinforced Composites for Engineering”, Bolton Institute, Bolton, England, 12-14 January, 1994.

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Impact strengths of injection moulded polypropylene long-glass-fibre composites

Paper (5) to the Institute of Materials 6th International Conference on Fibre Reinforced Composites, Newcastle, England, 29-31 March 1994.

Published in Plastics, Rubber and Composites Processing and Applications, Vol 24, No 3 (1995).
S F Bush with F B Yilmaz and P F Zhang

Abstract

A wide series of experiments has been undertaken to measure impact strength as a function of fibre length and concentration, the fibre/matrix interface, and induced fibre-mat structure and matrix properties. Both commercially-available long-fibre polypropylene granules and in-house polypropylene and polyethylene glass-fibre compounds have been used where the interface conditions are known and can be varied. For the fibre-mat structures achieved, notched impact strengths rise with fibre lengths and with fibre concentration, giving in all cases an improvement on the virgin polypropylenes – for some conditions a five-fold improvement at 25% w/w concentration.

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